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Self-organized Adhesion and Pattern Formation in Elastic Solid Films

Ashutosh Sharma

Department of Chemical Engineering, Indian Institute of Technology, Kanpur-208016

This talk will summarize some of our new results on the role of adhesion in pattern formation (1) and the role of patterns in adhesion (2) in soft elastic solid films. The adhesive contact induced patterns can be aligned and modulated (3) by varying the stamp separation distance, by using a patterned template, by a simple shear movement of the stamp, by use of multilayers or by application of an external e-field. Further, adhesive strength can be greatly modulated by surface or interior patterning of a soft elastic film (2). These results show an intimate relation between adhesion and structure at a soft interface and point to potential technological applications in self-organized meso-patterning (3) and fabrication of strong, reusable "structural" adhesives (2). The structural adhesives harness thermodynamic factors, rather than the kinetic factors such as visco-elasticity, to modulate the adhesive strength.

References
  1. Contact Instability in adhesion and debonding of thin elastic films, Phys. Rev. Lett. 97, 018303 (2006), and the earlier references therein to the phenomenon of the elastic contact instability.
  2. Micro-fluidic adhesion induced by sub-surface micro-structures, Science, 318, 258-261 (2007).
  3. Electric field induced instabilities and morphological phase transitions in soft elastic films, Phys. Rev. E 77, 031604 (2008); Contact instability of elastic bilayers: miniaturization of instability patterns, Adv. Func. Mat. 17, 2356-2364 (2007); Contact instability of thin elastic films on patterned substrates, J. Chem. Phys. 127, 064703 (2007); Self-organized meso-patterning of soft solids by controlled adhesion: elastic contact lithography, J. Nanosci. Nanotech. 7, 1744 (2007); Elastic contact induced self-organized patterning of hydrogel films, Macromolecules 39, 3365 (2006); Control of self-organized contact instability and patterning in soft elastic films, Langmuir 22, 7066 (2006); Electric field controlled surface instabilities in soft elastic films, Adv. Materials 18, 660 (2006).
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