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Dewetting Dynamics of Thin Polymer Films

By Elie Raphael

ESPCI, Paris

We study the dewetting of thin polymer films deposited on slippery substrate. Recent experiments by Reiter et al. and by Damman et al. on these systems have revealed many unexpected features. We develop here a model that takes into account the rheological properties of polymer melts, focussing on two dewetting geometries (the receding of a straight edge, and the opening of a hole). We show that the friction law associated with the slippage between the film and the substrate has a direct influence on the dewetting dynamic. In addition, we demonstrate that residual stresses, which can be stored in the films due to their viscoelasticity, are a source of destabilization for polymer films, and accelerate the dewetting process [work done in collaboration with T. Villemin, G. Reiter's group and P. Damman's group].

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